Photobiocatalytic decarboxylation for olefin synthesis.

نویسندگان

  • Ioannis Zachos
  • Sarah Katharina Gassmeyer
  • Daniel Bauer
  • Volker Sieber
  • Frank Hollmann
  • Robert Kourist
چکیده

Here, we describe the combination of OleTJE with a light-driven in situ H2O2-generation system for the selective and quantitative conversion of fatty acids into terminal alkenes. The photobiocatalytic system shows clear advantages regarding enzyme activity and yield, resulting in a simple and efficient system for fatty acid decarboxylation.

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عنوان ژورنال:
  • Chemical communications

دوره 51 10  شماره 

صفحات  -

تاریخ انتشار 2015